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Domino Effect in the Buildup of N‐I‐N‐I Chains of the N ‐Iodine(triphenylphosphane)imine
Author(s) -
Grebe Jutta,
Geiseler Gertraud,
Harms Klaus,
Neumüller Bernhard,
Dehnicke Kurt
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990115)38:1/2<222::aid-anie222>3.0.co;2-5
Subject(s) - tetramer , imine , domino , iodine , chemistry , ionic bonding , intermolecular force , crystallography , molecule , organic chemistry , catalysis , ion , enzyme
Up to the tetramer can be formed in a stepwise manner by an ionic domino mechanism by adding varying amounts of iodine to N ‐iodine(triphenylphosphane)imine, INPPh 3 , which does not exhibit intermolecular N⋅⋅⋅I contacts in the crystalline state. The tetramer [I(INPPh 3 ) 4 ] + I 3 − with alternatingly long N‐I‐N‐I bonds (see picture) is possibly not the last member of this series of new N‐I‐N associates.