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A Tricyclic, Organometallic Cage Molecule with a Tetraaminoethane Unit
Author(s) -
Veith Michael,
Schillo Bernhard,
Huch Volker
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990115)38:1/2<182::aid-anie182>3.0.co;2-m
Subject(s) - chemistry , tricyclic , cage , stereochemistry , molecule , protein subunit , azide , tin , group 2 organometallic chemistry , nitrogen , crystallography , organic chemistry , mathematics , biochemistry , combinatorics , gene
With elimination of nitrogen , a bis(amino)stannylene and an intramolecularly neighboring enediamine react with phenyl azide stereospecifically to form a molecular polycycle (see figure for structure), which in addition to silicon and tin also contains a tetraaminoethane subunit.