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UF 3+ —A Thermochemically Stable Diatomic Trication with a Covalent Bond
Author(s) -
Schröder Detlef,
Diefenbach Martin,
Klapötke Thomas M.,
Schwarz Helmut
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990115)38:1/2<137::aid-anie137>3.0.co;2-m
Subject(s) - diatomic molecule , ab initio , covalent bond , atomic physics , diagram , coulomb , chemistry , ab initio quantum chemistry methods , charge (physics) , ionic bonding , computational chemistry , physics , ion , molecule , nuclear physics , quantum mechanics , mathematics , organic chemistry , statistics , electron
Charge‐stripping mass spectrometry and ab initio calculations predict UF 3+ as the first diatomic trication which is thermochemically stable towards Coulomb explosion into U 2+ +F + . The corresponding energy diagram is depicted.