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The Hydrogen‐Bonded Framework of the First Anti‐Zeotype: [{(H 2 NEt 2 ) 2 } 2 (CuCl 4 )][AlCl 4 ]
Author(s) -
Martin James D.,
Leafblad Brian R.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981217)37:23<3318::aid-anie3318>3.0.co;2-y
Subject(s) - cationic polymerization , tetrahedron , crystallography , chemistry , cristobalite , materials science , polymer chemistry , metallurgy , quartz
Abstract A two‐coordinate cationic link between [CuCl 4 ] 3− tetrahedra by means of two inversion‐related dialkylammonium cations yields the hydrogen‐bonded A 2 X anti‐cristobalite framework [{(H 2 NEt 2 ) 2 } 2 (CuCl 4 )] + . This novel cationic framework is constructed around space‐filling and templating [AlCl 4 ] − anions resulting in large pores (16.6×6.7 Å).