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Solid‐Phase Synthesis and Encoding Strategies for Olefin Polymerization Catalyst Libraries
Author(s) -
Boussie Thomas R.,
Coutard Carla,
Turner Howard,
Murphy Vince,
Powers Timothy S.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981217)37:23<3272::aid-anie3272>3.0.co;2-r
Subject(s) - catalysis , diimine , polymerization , olefin fiber , solid phase synthesis , polymer , cleavage (geology) , chemistry , combinatorial chemistry , palladium , nickel , polymer chemistry , organic chemistry , materials science , biochemistry , peptide , composite material , fracture (geology)
Active polymerization catalysts , novel resin‐bound diimine complexes of nickel( II ) and palladium( II ) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer‐coated resin, HPLC can be used to determine the pathway along which the products were formed.