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Novel Cyanide Coordination Models in Layer‐Type Hydrated Double Salts of AgCN and AgF
Author(s) -
Guo GuoCong,
Mak Thomas C. W.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981204)37:22<3183::aid-anie3183>3.0.co;2-w
Subject(s) - cyanide , crystallography , cluster (spacecraft) , type (biology) , chemistry , layer (electronics) , moiety , stereochemistry , materials science , nanotechnology , inorganic chemistry , computer science , geology , programming language , paleontology
The edge‐bridged triangular cluster [Ag 3 ( μ ‐CN) 3 (H 2 O) 3 ] (left in picture) and the pseudo‐cubane moiety [Ag 3 F(H 2 O) 3 ] with an unoccupied Ag position (right in picture)—both hitherto unknown—are found in two new layer‐type double salts of AgCN and AgF that display novel types of cyanide coordination modes.