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An Unprecedented Elimination‐Driven Migration: The Reductive Dihalobornane–Camphene Rearrangement
Author(s) -
Garamszegi László,
Schlosser Manfred
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981204)37:22<3173::aid-anie3173>3.0.co;2-y
Subject(s) - camphene , neuroscience , psychology , chemistry , chromatography , essential oil
An organometallic counterpart of the Wagner–Meerwein rearrangement, the incarnation of an carbocationic alkyl 1,2‐migration, has now been discovered. However, the structural reorganization does not occur through carbanionic intermediates, but can only be brought about by a push–pull process via 1 a (see scheme).