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Alkylation of Porous Silicon by Direct Reaction with Alkenes and Alkynes
Author(s) -
Bateman James E.,
Eagling Robert D.,
Worrall David R.,
Horrocks Benjamin R.,
Houlton Andrew
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981016)37:19<2683::aid-anie2683>3.0.co;2-y
Subject(s) - porous silicon , silicon , hydrosilylation , alkylation , porosity , hydrogen , materials science , chemistry , chemical engineering , photochemistry , catalysis , organic chemistry , engineering
The hydrogen‐terminated surface of porous silicon (PS) is sufficiently reactive for the uncatalyzed hydrosilation of alkenes and alkynes. These modifications produce dramatic changes to both the physical and chemical properties of the PS.