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Molecular Model for Aluminophosphates Containing Fluoride as a Structure‐Directing and Mineralizing Agent
Author(s) -
Yang Yu,
Pinkas Jiri,
Schäfer Martina,
Roesky Herbert W.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981016)37:19<2650::aid-anie2650>3.0.co;2-l
Subject(s) - microporous material , ring (chemistry) , chemistry , fluoride , inorganic chemistry , organic chemistry
Two tricyclic capped six‐rings (C6R), a double four‐ring (D4R), and an Al( μ ‐F) 2 Al unit are among the structural features of 1 (see picture for structure) that are closely related to motifs found in layered and three‐dimensional alumino‐ and gallophosphates. Several reactive centers can render 1 a viable precursor for the synthesis of microporous aluminophosphates.