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Time‐Resolved IR‐Thermographic Detection and Screening of Enantioselectivity in Catalytic Reactions
Author(s) -
Reetz Manfred T.,
Becker Michael H.,
Kühling Klaus M.,
Holzwarth Arnold
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981016)37:19<2647::aid-anie2647>3.0.co;2-i
Subject(s) - catalysis , thermography , chemistry , combinatorial chemistry , infrared , lipase , organic chemistry , materials science , optics , physics , enzyme
Simple monitoring of lipase‐ and transition metal catalyzed asymmetric esterifications [Eq. (1)] and opening of epoxides [Eq. (2)] can be achieved by IR thermography. Thus, a new method is available for screening of enantioselectivity in catalytic reactions.