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Quadruple Decker [3.3][3.3][3.3]Orthocyclophane Acetal—An Orthocyclophane Ladder
Author(s) -
Mataka Shuntaro,
Shigaki Kouichiro,
Sawada Tsuyoshi,
Mitoma Yoshihara,
Taniguchi Masahiko,
Thiemann Thies,
Ohga Kazuya,
Egashira Naoyoshi
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19981002)37:18<2532::aid-anie2532>3.0.co;2-r
Subject(s) - bridging (networking) , acetal , molecule , benzene , electrochemistry , face (sociological concept) , crystallography , chemistry , stereochemistry , materials science , computer science , organic chemistry , electrode , philosophy , computer network , linguistics
Through clever bridging of orthocyclophanes (in this case by acetalization), molecules such as 1 can be formed with four benzene rings in a stacked face‐to‐face arrangement. UV/Vis spectroscopic and electrochemical properties of 1 are governed by π–π through‐space interactions within the molecule.