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The π‐Pyrrole Complexation of Alkali Metal Ions by Zirconium meso ‐Octaalkylporphyrinogens: Encapsulation of Li 4 H 4 and Li 2 O in Sandwich Structures
Author(s) -
Floriani Carlo,
Solari Euro,
Solari Giovanna,
ChiesiVilla Angiola,
Rizzoli Corrado
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980904)37:16<2245::aid-anie2245>3.0.co;2-j
Subject(s) - counterion , alkali metal , bifunctional , zirconium , chemistry , inorganic chemistry , ion , metal , pyrrole , metal ions in aqueous solution , polymer chemistry , organic chemistry , catalysis
Abstract Complexation of metal ion and counterion by the same compound is possible with zirconium meso ‐octaalkylporphyrinogens (structure of a dimeric complex with four encapsulated equivalents of LiH is depicted): they carry salts in the molecular ion‐pair form in hydrocarbons, and function as acid–base bifunctional compounds.