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Photoluminescent Rigid Molecular Rods with Cumulenic C n ( n =3, 4) Spacers: Modulation of Electronic Interaction
Author(s) -
Hong Bo,
Ortega Jeffrey V.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980817)37:15<2131::aid-anie2131>3.0.co;2-a
Subject(s) - metal , rod , photoluminescence , electronic communication , modulation (music) , electronic structure , redox , materials science , bridge (graph theory) , crystallography , chemistry , photochemistry , inorganic chemistry , computational chemistry , optoelectronics , physics , metallurgy , telecommunications , computer science , medicine , alternative medicine , pathology , acoustics
Varying the length of the carbon chain in the bridge of complexes of types 1 and 2 can influence the photophysical properties and redox potentials of the metal centers as well as the electronic communication between these metal centers (M=Ru, Os; bpy=2,2′‐bipyridine).