Premium
Metal—‐Metal “Communication” of Rh or Pd with Nd in Novel Heterobinuclear Complexes
Author(s) -
Spannenberg Anke,
Oberthür Markus,
Noss Henrik,
Tillack Annegret,
Arndt Perdita,
Kempe Rhett
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980817)37:15<2079::aid-anie2079>3.0.co;2-y
Subject(s) - lanthanide , metal , salt (chemistry) , neodymium , transition metal , chemistry , chloride , inorganic chemistry , catalysis , laser , organic chemistry , optics , physics , ion
Abstract The reaction of a neodymium “ate” complex and an electron‐rich transition metal chloride by salt elimination is an efficient method for synthesizing heterobinuclear compounds which contain a lanthanide and a Group 9 or 10 metal [Eq. (1), H 2 Ap=2‐amino‐4‐methylpyridine]. The use of bisaminopyridinato ligands allows extremely short distances between Rh or Pd and Nd.