Metal—‐Metal “Communication” of Rh or Pd with Nd in Novel Heterobinuclear Complexes | Zendy

Spannenberg Anke | Zendy; Oberthür Markus | Zendy; Noss Henrik | Zendy; Tillack Annegret | Zendy; Arndt Perdita | Zendy; Kempe Rhett | Zendy

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Metal—‐Metal “Communication” of Rh or Pd with Nd in Novel Heterobinuclear Complexes

Author(s) -

Spannenberg Anke,

Oberthür Markus,

Noss Henrik,

Tillack Annegret,

Arndt Perdita,

Kempe Rhett

Publication year - 1998

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/(sici)1521-3773(19980817)37:15<2079::aid-anie2079>3.0.co;2-y

Subject(s) - lanthanide , metal , salt (chemistry) , neodymium , transition metal , chemistry , chloride , inorganic chemistry , catalysis , laser , organic chemistry , optics , physics , ion

The reaction of a neodymium “ate” complex and an electron‐rich transition metal chloride by salt elimination is an efficient method for synthesizing heterobinuclear compounds which contain a lanthanide and a Group 9 or 10 metal [Eq. (1), H 2 Ap=2‐amino‐4‐methylpyridine]. The use of bisaminopyridinato ligands allows extremely short distances between Rh or Pd and Nd.

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