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Secondary Bonding between Chalcogens or Pnicogens and Halogens
Author(s) -
Landrum Gregory A.,
Hoffmann Roald
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980803)37:13/14<1887::aid-anie1887>3.0.co;2-0
Subject(s) - chalcogen , hypervalent molecule , halogen , halogen bond , acceptor , chemistry , crystallography , center (category theory) , group (periodic table) , solid state , electron acceptor , materials science , physics , organic chemistry , condensed matter physics , reagent , alkyl
An intimate connection between bonding types that are at times characterized as electron‐rich three‐center, as hypervalent, as secondary, or as donor–acceptor in the solid state is found in the quasi‐linear X‐Q‐X systems (X=halogen, Q=chalcogen or element of Group 15).

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