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Symmetry‐Driven Rational Design of a Tetrahedral Supramolecular Ti 4 L 4 Cluster
Author(s) -
Brückner Christian,
Powers Ryan E.,
Raymond Kenneth N.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980803)37:13/14<1837::aid-anie1837>3.0.co;2-a
Subject(s) - tetrahedron , symmetry (geometry) , tetrahedral symmetry , supramolecular chemistry , cluster (spacecraft) , rational design , design elements and principles , theoretical physics , crystallography , mathematics , materials science , pure mathematics , chemistry , physics , rotational symmetry , computer science , nanotechnology , geometry , crystal structure , software engineering , programming language
General design principles for the formation of tetrahedral M 4 L 4 clusters (L=ligand) are outlined and exemplified by the formation and structure of the [Ti 4 L 4 ] 8− species pictured on the right.