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Partially Oxidized Zintl Ions? The Characterization of [( μ 3 ‐OH)( μ 3 ‐O) 3 (OEt) 3 {(CO) 5 W} 7 Sn 7 ] 2−
Author(s) -
Kircher Peter,
Huttner Gottfried,
Zsolnai Laszlo,
Driess Alexander
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980703)37:12<1666::aid-anie1666>3.0.co;2-v
Subject(s) - ion , characterization (materials science) , chemistry , crystallography , materials science , nanotechnology , organic chemistry
A formally isoelectronic ( μ 3 ‐Sn) 2− ion replaces the μ 3 ‐O building block in the subvalent anion 1 , which is a derivative of the known cage compound [( μ 3 ‐OR) 4 ( μ 3 ‐O) 4 Sn 6 ]. Thus, compound 1 forms a link between oxo metal clusters and Zintl ions. [( μ 3 ‐OH)( μ 3 ‐O) 3 (OEt) 3 {(CO) 5 W} 7 Sn 7 ] 2−1