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Alkylidyne–Metal Templated Triboronate Condensation
Author(s) -
Dyson Paul J.,
Hill Anthony F.,
Hulkes Alexander G.,
White Andrew J. P.,
Williams David J.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980605)37:10<1430::aid-anie1430>3.0.co;2-c
Subject(s) - condensation , metal , chemistry , condensation reaction , polymer chemistry , organic chemistry , catalysis , physics , thermodynamics
Under exceptionally mild conditions the alkylidyne metallatetraborane 1 undergoes an intriguing conversion into the dodecaboronate dianion in a rare example of metal‐templated boronate condensation.