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Reaction of Group 15 Trichlorides ECl 3 with the Anion [Mo 2 Cp 2 (CO) 4 ( μ ‐PH 2 )] − ; Synthesis and Characterization of the First Complexes Featuring a Hetero μ , η 2 ‐PE ligand (E=As, Sb)
Author(s) -
Davies John E.,
Kerr Lesley C.,
Mays Martin J.,
Raithby Paul R.,
Tompkin Peter K.,
Woods Anthony D.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980605)37:10<1428::aid-anie1428>3.0.co;2-3
Subject(s) - antimony , chemistry , arsenic , ligand (biochemistry) , group (periodic table) , characterization (materials science) , ion , medicinal chemistry , stereochemistry , inorganic chemistry , polymer chemistry , organic chemistry , receptor , nanotechnology , materials science , biochemistry
An Me 2 PE tetrahedrane framework is seen in complexes 2 a – c (E=P, As, Sb), which are prepared from the appropriate trichlorides and 1 in THF. The structures of the new antimony‐ and arsenic‐containing compounds 2 b and 2 c have been determined—this is the first structural characterization of complexes with μ , η 2 ‐PE heteroligands from elements of Group 15.