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Novel Bonding of Iodine: Crystal Structure of HIS 2 O 8
Author(s) -
Jansen Martin,
Müller Ralph
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980605)37:10<1426::aid-anie1426>3.0.co;2-f
Subject(s) - sulfuric acid , iodine , protonation , crystal structure , tetrahedron , sulfate , chemistry , crystallography , polymer chemistry , inorganic chemistry , organic chemistry , ion
Iodine bridges two sulfate tetrahedra in the title compound and therefore participates in unusual and novel bonding. The structure of the compound (section shown on the right) can be regarded as the result of a condensation reaction between the protonated form of the hypothetical iodic( III ) acid, sulfuric acid, and hydrogensulfate.