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Synthesis and Association Behavior of [4.4.4.4.4.4]Metacyclophanedodecayne Derivatives with Interior Binding Groups
Author(s) -
Tobe Yoshito,
Utsumi Naoto,
Nagano Atsushi,
Naemura Koichiro
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980518)37:9<1285::aid-anie1285>3.0.co;2-b
Subject(s) - association (psychology) , chemistry , stereochemistry , psychology , psychotherapist
Intriguing association behavior in solution is exhibited by the rigid macrocycle 1 . For instance, it reacts with organic cations to give ternary complexes of the composition ( 1 ⋅cation)⋅ 1 , and with analogous macrocycles without cyano groups it forms heteroaggregates. R=CO 2 C 8 H 17 .