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Generation of “Naked” Fluoride Ions in Unprecedentedly High Concentrations from a Fluoropalladium Complex
Author(s) -
Grushin Vladimir V.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980420)37:7<994::aid-anie994>3.0.co;2-h
Subject(s) - fluoride , ion , chemistry , inorganic chemistry , organic chemistry
An F − /Cl − ligand exchange in the stable organopalladium fluoro complex 1 generates naked fluoride ions in unusually high concentrations. The released F − readily fluorinates dichloromethane under exceedingly mild conditions and deprotonates chloroform to produce dichlorocarbene.