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Ni[In{C(SiMe 3 ) 3 } 4 ]: An Organometallic Nickel–Indium Compound Analogous to [Ni(CO) 4 ]
Author(s) -
Uhl Werner,
Pohlmann Michael,
Wartchow Rudolf
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980420)37:7<961::aid-anie961>3.0.co;2-4
Subject(s) - nickel , chemistry , carbon monoxide , indium , group 2 organometallic chemistry , nickel compounds , ligand (biochemistry) , carbon atom , organometallic chemistry , atom (system on chip) , stereochemistry , combinatorial chemistry , crystallography , catalysis , crystal structure , organic chemistry , molecule , ring (chemistry) , biochemistry , receptor , computer science , embedded system
The highly symmetric title compound contains a Ni atom that is tetrahedrally coordinated by four alkylindium( I ) ligands InC(SiMe 3 ) 3 . The ligand InR is isolobal with carbon monoxide, and the product is thus a remarkable addition to the class of [Ni(CO) 4 ] analogues.