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A Simple Preparative Route to Bis(imido)uranium( VI ) Complexes by the Direct Reductions of Diazenes and Azides
Author(s) -
Warner Benjamin P.,
Scott Brian L.,
Burns Carol J.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980420)37:7<959::aid-anie959>3.0.co;2-d
Subject(s) - chemistry , uranium , actinide , metallocene , combinatorial chemistry , organic chemistry , inorganic chemistry , materials science , metallurgy , polymerization , polymer
In clean, one‐pot procedures , the uranium complex 1 reductively cleaves azides and azo compounds to generate bis(imido) derivatives [Eq. (a)]. This unusual reaction has not been observed previously in either the actinide series or with a metallocene complex.