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Yttrate‐Mediated Ligand Transfer and Direct Synthesis as a Route to Amidopalladium Complexes
Author(s) -
Spannenberg Anke,
Arndt Perdita,
Kempe Rhett
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980403)37:6<832::aid-anie832>3.0.co;2-a
Subject(s) - palladium , ligand (biochemistry) , yttrium , cyclooctadiene , chemistry , transition metal , combinatorial chemistry , catalysis , organic chemistry , receptor , oxide , biochemistry
A ligand transfer from yttrium to palladium and the regeneration of 1 are the crucial steps in the efficient synthesis of the very strained amidopallium complex 2 from [(cod)PdCl 2 ] and 1 (cod=cyclooctadiene). In the light of the numerous “ate” complexes of early transition metals, this synthetic route should have enormous potential.