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A Fully Encapsulated Acetylenediide in Ag 2 C 2 ⋅8 AgF
Author(s) -
Guo GuoCong,
Zhou GongDu,
Wang QiGuang,
Mak Thomas C. W.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980316)37:5<630::aid-anie630>3.0.co;2-k
Subject(s) - computer science
The reaction of Ag 2 C 2 with a concentrated aqueous solution of AgF leads to the title compound, in which the dianion C 2 2− is completely enclosed in the Ag 9 cage of a chandelierlike arrangement of ten silver atoms.