Premium
A Bifunctional Lewis Acidic Spacer in Self‐Assembled Molecular Stairs and Ladders
Author(s) -
Gabbaï François P.,
Schier Annette,
Riede Jürgen
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980316)37:5<622::aid-anie622>3.0.co;2-g
Subject(s) - bifunctional , pyrazine , stairs , self assembly , polymer , materials science , chemistry , polymer chemistry , nanotechnology , crystallography , stereochemistry , organic chemistry , engineering , composite material , catalysis , structural engineering
Abstract Depending on the stoichiometry , diindacycle 1 and pyrazine in THF reversibly form a stair‐ or a ladderlike self‐organized coordination polymer. In both cases, the building blocks are assembled at angles close to 90°.