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[Mo 12 S 12 O 12 (OH) 12 (H 2 O) 6 ]: A Cyclic Molecular Cluster Based on the [Mo 2 S 2 O 2 ] 2+ Building Block
Author(s) -
Cadot Emmanuel,
Salignac Bernadette,
Halut Sabine,
Sécheresse Francis
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980316)37:5<611::aid-anie611>3.0.co;2-o
Subject(s) - block (permutation group theory) , cluster (spacecraft) , computer science , chemistry , mathematics , combinatorics , programming language
The pH‐dependent self‐condensation of the [Mo 2 S 2 O 2 ] 2+ complex fragment gives the wheellike Mo 12 cluster depicted on the right (ball‐and‐stick model; large balls: S, medium balls: O, small balls: Mo). Applying this synthetic strategy to other starting materials could provide access to other polyoxothiometalates with well‐defined cavities.