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Ti 2 Nb 6 Cl 14 O 4 : A Unique 2D–1D Network Combination in Niobium Cluster Chemistry
Author(s) -
Anokhina Ekaterina V.,
Essig Michael W.,
Lachgar Abdessadek
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980302)37:4<522::aid-anie522>3.0.co;2-y
Subject(s) - niobium , cluster (spacecraft) , materials science , chemistry , computer science , computer network , metallurgy
Layers of niobium clusters that are linked to each other through zigzag chains of edge‐sharing [TiCl 4 O 2 ] ocatahedra are the central structural features of the title compound. Bridging of the chains by [(Nb 6 Cl 8 i O 4 i )Cl 6 a ] 6− clusters results in the formation of empty tunnels (a section of the structure is shown on the right).