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First Isolation and Structural Characterization of a Nickel( III ) Complex Containing Aliphatic Thiolate Donors
Author(s) -
Hanss Jan,
Krüger HansJörg
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980216)37:3<360::aid-anie360>3.0.co;2-p
Subject(s) - nickel , chemistry , ligand (biochemistry) , decomposition , salt (chemistry) , characterization (materials science) , stereochemistry , polymer chemistry , organic chemistry , materials science , nanotechnology , biochemistry , receptor
Long overdue were syntheses of nickel( III ) complexes containing aliphatic thiolate ligands. The complex anion [Ni(phmi)] − (phmi is the tetraanion of N , N ′‐1,2‐phenylenebis(2‐methyl‐2‐sulfanylpropionamide) has now been isolated—as PPh 4 salt—and structurally characterized. The stability of the nickel( III ) complex is attributed to the special properties of the ligand, which abolish or at least retard possible decomposition pathways.