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Crystal Structures of Chiral Diastereoisomers of a Carbon‐Based High‐Spin Molecule
Author(s) -
Sedó Josep,
Ventosa Nora,
RuizMolina Daniel,
Mas Montserrat,
Molins Elies,
Rovira Concepció,
Veciana Jaume
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980216)37:3<330::aid-anie330>3.0.co;2-0
Subject(s) - diastereomer , asymmetric carbon , molecule , crystal structure , crystal (programming language) , crystallography , chemistry , spin (aerodynamics) , resolution (logic) , stereochemistry , optically active , physics , organic chemistry , thermodynamics , artificial intelligence , computer science , programming language
A chiral organic compound that displays magnetic properties has been synthesized for the first time. Two diastereomers of a molecule having an S =3/2 spin state have been characterized by X‐ray crystal structure analysis (one of the diastereomers is shown in the space‐filling model on the right). Optical resolution of one pair of stereoisomers was possible by chiral stationary phase HPLC.