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β ‐Homoalanyl PNAs: Synthesis and Indication of Higher Ordered Structures
Author(s) -
Diederichsen Ulf,
Schmitt Harald W.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980216)37:3<302::aid-anie302>3.0.co;2-4
Subject(s) - chemistry , derivative (finance) , mitsunobu reaction , pairing , combinatorial chemistry , stereochemistry , purine , amino acid , homoserine , organic chemistry , biochemistry , quorum sensing , enzyme , physics , superconductivity , quantum mechanics , financial economics , economics , virulence , gene
Self‐pairing complexes with extraordinarily high stability are formed by β ‐PNAs with four to six units of the nucleo‐ β ‐amino acid 1 . The key step in the synthesis is a Mitsunobu reaction between a β ‐homoserine and a purine derivative.