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First Isolation and Structural Characterization of Bis(Anthracene)Metal Complexes: [Ti( η 6 ‐C 14 H 10 )( η 4 ‐C 14 H 10 )( η 2 ‐dmpe)] and [Ti( η 4 ‐C 14 H 10 )( η 2 ‐C 14 H 10 )( η 5 ‐C 5 Me 5 )] −
Author(s) -
Seaburg John K.,
Fischer Paul J.,
Young, Jr. Victor G.,
Ellis John E.
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980202)37:1/2<155::aid-anie155>3.0.co;2-x
Subject(s) - anthracene , metal , chemistry , crystal structure , characterization (materials science) , crystallography , solid state , stereochemistry , photochemistry , materials science , organic chemistry , nanotechnology
Two anthracene ligands, each coordinated differently are contained in the first two structurally characterized bis(anthracene) complexes of a Group 4 metal. Crystal structure analyses of [Ti( η 6 ‐C 14 H 10 )( η 4 ‐C 14 H 10 )( η 2 ‐dmpe)] (dmpe=1,2 ‐ bis ( dimethylphosphino ) ethane) and [Ti( η 4 ‐C 14 H 10 )( η 2 ‐C 14 H 10 )( η 5 ‐C 5 Me 5 )] − (see picture) show that they have unusual and completely different structures in the solid state.