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Well‐Defined Surface‐Bonded Ruthenium Complexes with Molecular Nitrogen
Author(s) -
Miessner Hans,
Richter Klaus
Publication year - 1998
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19980202)37:1/2<117::aid-anie117>3.0.co;2-4
Subject(s) - ruthenium , molecular nitrogen , nitrogen , catalysis , zeolite , chemistry , photochemistry , organic chemistry
Stable up to 523 K , the bis(dinitrogen) ruthenium and carbonyldinitrogen ruthenium complexes are formed by reaction of N 2 with a carbonyl ruthenium species fixed on dealuminated Y zeolite [Eq. (a)]. A stable trans ‐dicarbonyldinitrogen ruthenium complex is also formed in the presence of CO at 300 K.