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Are the Approach Directions of σ and π Nucleophiles to the Sulfur Atom of Thiiranium and Thiirenium Ions Different?
Author(s) -
Sølling Theis I.,
Wild S. Bruce,
Radom Leo
Publication year - 2000
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(20000218)6:4<590::aid-chem590>3.0.co;2-e
Subject(s) - nucleophile , sulfur , ion , atom (system on chip) , chemistry , computational chemistry , organic chemistry , computer science , catalysis , parallel computing
A collinear approach to the sulfur atom of thiiranium and thiirenium ions (see scheme) is predicted by theoretical calculations for both σ and π nucleophiles.