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Lead Hydro Sodalite [Pb 2 (OH)(H 2 O) 3 ] 2 [Al 3 Si 3 O 12 ] 2 : Synthesis and Structure Determination by Combining X‐ray Rietveld Refinement, 1 H MAS NMR FTIR and XANES Spectroscopy
Author(s) -
EidenAßmann Stefanie,
Schneider A. M.,
Behrens Peter,
Wiebcke Michael,
Engelhardt Günter,
Felsche Jürgen
Publication year - 2000
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(20000117)6:2<292::aid-chem292>3.0.co;2-m
Subject(s) - sodalite , rietveld refinement , crystallography , chemistry , xanes , hydrogen bond , infrared spectroscopy , crystal structure , lone pair , inorganic chemistry , spectroscopy , molecule , zeolite , catalysis , biochemistry , physics , organic chemistry , quantum mechanics
The same novel, orientationally disordered lead complex , [Pb 2 (OH)(H 2 O) 3 ] 2 [Al 3 Si 3 O 12 ] 2 , was obtained by ion exchange of various sodium hydro sodalites with aqueous Pb(NO 3 ) 2 solutions, whichever sodalite reactant was used. A model of the structure was developed, as illustrated.