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Chiral Bis(dihydrooxazolyl)pyridineruthenium Complexes of trans ‐Cyclooctene and trans ‐Cycloheptene
Author(s) -
Nishiyama Hisao,
Naitoh Tomonari,
Motoyama Yukihiro,
Aoki Katsuyuki
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19991203)5:12<3509::aid-chem3509>3.0.co;2-2
Subject(s) - cycloheptene , cyclooctene , enantiomer , chemistry , stereochemistry , organic chemistry , catalysis
Abstract The chiral {RuCl 2 (pybox‐ ip )} fragment can selectively capture the R enantiomer of racemic trans ‐cyclooctene 1 to give the corresponding complex 2 (see figure) and the free S enantiomer. The crystal structure of 2 is determined by X‐ray analysis.