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Studies on the Biomimetic Synthesis of the Manzamine Alkaloids
Author(s) -
Baldwin Jack E.,
Claridge Timothy D. W.,
Culshaw Andrew J.,
Heupel Florian A.,
Lee Victor,
Spring David R.,
Whitehead Roger C.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19991105)5:11<3154::aid-chem3154>3.0.co;2-7
Subject(s) - chemistry , stereochemistry
Intramolecular Diels–Alder reaction of a simple macrocyclic bis‐dihydropyridine precursor 1 resulted in the formation of a complex marine alkaloid keramaphidin B, thus verifying a biosynthetic theory.