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Solid‐State Architectures of Aggregates of the Cubic Cluster [Pd 6 Cl 12 ] with Polynuclear Aromatic Hydrocarbons
Author(s) -
Olmstead Marilyn M.,
Wei Pinpin,
Balch Alan L.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19991105)5:11<3136::aid-chem3136>3.0.co;2-#
Subject(s) - cluster (spacecraft) , solid state , chemistry , state (computer science) , chemical engineering , computer science , engineering , programming language , algorithm
Deeply colored, air‐stable molecular crystals , [Pd 6 Cl 12 ]⋅1.5 (naphthalene), [Pd 6 Cl 12 ]⋅(1‐methylanthracene), and [Pd 6 Cl 12 ]⋅0.5 (1,2:5,6‐dibenzanthracene)⋅0.5 (benzene) (shown here) consisting of planar polynuclear aromatic hydrocarbon (PAH) molecules and cubic clusters of [Pd 6 Cl 12 ] are readily formed from solutions of bis(benzonitrile)palladium( II ) dichloride and the approriate PAH in benzene.