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Reversible Binding of Dioxygen by a Copper( I ) Complex with Tris(2‐dimethylaminoethyl)amine (Me 6 tren) as a Ligand
Author(s) -
Becker Michael,
Heinemann Frank W.,
Schindler Siegfried
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19991105)5:11<3124::aid-chem3124>3.0.co;2-d
Subject(s) - amine gas treating , tris , copper , ligand (biochemistry) , chemistry , oxygen , polymer chemistry , crystallography , photochemistry , organic chemistry , biochemistry , receptor
A reversible reaction with dioxygen is observed for the copper( I ) complex [Cu(Me 6 tren)] + (Me 6 tren=tris(2‐dimethylaminoethyl)amine) at low temperatures. This complex displays an interesting crystal structure (depicted) and the interaction with dioxygen in solution was investigated by low‐temperature UV/Vis spectroscopic methods.