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Reactions of trans ‐5‐Palladatricyclo[4.1.0.0 2,4 ]heptanes: Stereoselective Formation of Highly Substituted 1,1′‐Bi(cyclopropyl) Compounds and (3 Z )‐1,3,5‐Hexatrienes
Author(s) -
Hashmi A. Stephen K.,
Naumann Frank,
Rivas Nass Andreas,
Degen Alexander,
Bolte Michael,
Bats Jan W.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19991001)5:10<2836::aid-chem2836>3.0.co;2-c
Subject(s) - palladium , stereoselectivity , reagent , chemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , catalysis
Depending upon the reagent , the trans ‐5‐palladatricyclo[4.1.0.0 2,4 ]heptanes lead either to bi(cyclopropyl) compounds or to ( Z )‐hexatrienes. All possible pathways for these reactions involve palladacyles in oxidation states palladium( III ) or palladium( IV ).