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Globular Dendrimers Involving a C 60 Core and a Tetraphenyl Porphyrin Function
Author(s) -
Camps Xavier,
Dietel Elke,
Hirsch Andreas,
Pyo Soomi,
Echegoyen Luis,
Hackbarth Steffen,
Röder Beate
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990802)5:8<2362::aid-chem2362>3.0.co;2-5
Subject(s) - dendrimer , porphyrin , chromophore , tetraphenylporphyrin , heme , chemistry , zinc , globular protein , core (optical fiber) , redox , photochemistry , crystallography , materials science , polymer chemistry , organic chemistry , composite material , enzyme
The nanoenvironment provided by the neighboring dendra characteristically influences the redox potentials and the photophysical properties of the tetraphenylporphyrin–zinc (Zn‐TPP; denoted as P in Figure) chromophore within the dendrimers 1 , which are based on C 60 as a structure‐determining core. Such functional dendrimers represent a new prototype of model systems for heme proteins ( 1 ).