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Crystal Structure and Magnetic Properties of the Quasi‐One‐Dimensional Compound (Ca 1− x Y x ) 0.82 CuO 2 Prepared at Room Pressure
Author(s) -
Miyazaki Yuzuru,
Hyatt Neil C.,
Slaski Marcin,
Gameson Ian,
Edwards Peter P.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990802)5:8<2265::aid-chem2265>3.0.co;2-u
Subject(s) - paramagnetism , crystallography , materials science , crystal structure , spin (aerodynamics) , condensed matter physics , cuprate , solid state , crystal (programming language) , range (aeronautics) , chemistry , physics , superconductivity , composite material , thermodynamics , computer science , programming language
Across a solid‐solution range of a self‐assembled and crystal‐engineered quasi‐one‐dimensional cuprate compound [(Ca 1− x Y x ) 0.82 CuO 2 ], spanning from Cu 2.00+ to Cu 2.36+ , the system continuously transforms from a long‐range antiferromagnetically (AF) ordered state (at Cu 2.00+ ) to a complex magnetic regime, consisting of spin dimers ( S =0) and paramagnetic spin segments ( S =1/2), see illustration.