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meso ‐Octaethylporphyrinogen Displaying Site Selectivity in the Stepwise Synthesis of Polymetallic Aggregates with Interesting Redox Properties: The π‐Binding Ability of Metalla‐Porphyrinogens
Author(s) -
Bonomo Lucia,
Solari Euro,
Latronico Mario,
Scopelliti Rosario,
Floriani Carlo
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990702)5:7<2040::aid-chem2040>3.0.co;2-4
Subject(s) - intramolecular force , redox , selectivity , chemistry , combinatorial chemistry , stereochemistry , catalysis , inorganic chemistry , organic chemistry
The sequential reaction of meso ‐octaethylporphyrinogen tetraanion with Ni II followed by Co II , Ru II , Ni II allowed the build up of mixed coordination organometallic aggregates such as 1 , which undergo thermally, chemically, or photochemically induced intramolecular electron transfers.