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Furanosylidene and Iminofuranosylidene Complexes: Synthesis by Stoichiometric Olefin Metathesis and Ring‐Opening/Mitsunobu‐Recyclization Sequence
Author(s) -
Haase WilmChristian,
Nieger Martin,
Dötz Karl Heinz
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990702)5:7<2014::aid-chem2014>3.0.co;2-n
Subject(s) - aminolysis , olefin metathesis , sequence (biology) , ring (chemistry) , mitsunobu reaction , olefin fiber , metathesis , stoichiometry , chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , polymer , polymerization
Transition metal activated furanosylidenes and iminofuranosylidenes are accessible by stoichiometric olefin metathesis and a ring‐opening aminolysis/Mitsunobu recyclization sequence. The methodology has been applied to the synthesis of novel organometallic glycoconjugates (see picture).

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