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Fluorous Biphasic Catalysis: A New Paradigm for the Separation of Homogeneous Catalysts from Their Reaction Substrates and Products
Author(s) -
Fish Richard H.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990604)5:6<1677::aid-chem1677>3.0.co;2-x
Subject(s) - catalysis , homogeneous , homogeneous catalysis , substrate (aquarium) , solubility , phase (matter) , chemistry , fine chemical , chemical engineering , combinatorial chemistry , materials science , organic chemistry , engineering , physics , thermodynamics , oceanography , geology
A new paradigm for homogeneous catalytic reactions , fluorous biphasic catalysis, simplifies the separation technique of the phase‐containing substrate and product from the modified fluoroponytailed catalyst, which has total fluorous phase solubility, as shown here.