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Synthesis of Disaccharides, Containing Sulfur in the Ring of the Reducing Monosaccharide Unit, Through a Nonglycosylating Chemical Strategy
Author(s) -
IsacGarcía Joaquín,
CalvoFlores Francisco G.,
HernándezMateo Fernando,
SantoyoGonzález Francisco
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990503)5:5<1512::aid-chem1512>3.0.co;2-a
Subject(s) - maltose , chemistry , cellobiose , monosaccharide , ring (chemistry) , lactose , disaccharide , sulfur , sugar , organic chemistry , residue (chemistry) , vicinal , stereochemistry , sucrose , cellulose , cellulase
A novel ring‐opening–recyclisation approach of the nonreducing sugar residue is reported for the formation of thio sugars from vicinal diols of natural disaccharides (lactose, maltose and cellobiose; see scheme), via cyclic sulfates.