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Giant Ring‐Shaped Building Blocks Linked to Form a Layered Cluster Network with Nanosized Channels: [Mo 124 VI Mo 28 V O 429 ( μ 3 ‐O) 28 H 14 (H 2 O) 66.5 ] 16−
Author(s) -
Müller Achim,
Krickemeyer Erich,
Bögge Hartmut,
Schmidtmann Marc,
Beugholt Christian,
Das Samar K.,
Peters Frank
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990503)5:5<1496::aid-chem1496>3.0.co;2-d
Subject(s) - molybdate , sodium molybdate , cluster (spacecraft) , aqueous solution , salt (chemistry) , ring (chemistry) , block (permutation group theory) , materials science , chemistry , nanotechnology , crystallography , computer science , inorganic chemistry , geometry , mathematics , organic chemistry , computer network
A novel type of electron‐rich (basic!) nanosized channels can be built up by linking giant ring‐shaped building blocks, which occur in the layered compound of composition [Mo 124 VI Mo 28 V O 429 ( μ 3 ‐O) 28 H 14 (H 2 O) 66.5 ] 16− (see figure). The corresponding sodium salt is obtained by reduction of an acidified aqueous molybdate solution under special reaction conditions.