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B ‐Alkylcatecholboranes as a Source of Radicals for Efficient Conjugate Additions to Unsaturated Ketones and Aldehydes
Author(s) -
Ollivier Cyril,
Renaud Philippe
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990503)5:5<1468::aid-chem1468>3.0.co;2-7
Subject(s) - conjugate , radical , chemistry , organic chemistry , mathematics , mathematical analysis
Selective generation of radicals from organoboranes is reported. A simple one‐pot procedure involving a hydroboration with catecholborane followed by a radical reaction has been developed (see equation).