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Intramolecular Se⋅⋅⋅N Nonbonding Interactions in Low‐Valent Organoselenium Derivatives: A Detailed Study by 1 H and 77 Se NMR Spectroscopy and X‐ray Crystallography
Author(s) -
Mugesh G.,
Panda Arunashree,
Singh Harkesh B.,
Butcher Ray J.
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990503)5:5<1411::aid-chem1411>3.0.co;2-m
Subject(s) - intramolecular force , chemistry , nuclear magnetic resonance spectroscopy , crystallography , x ray , stereochemistry , physics , quantum mechanics
A series of novel low‐valent organoselenium compounds stabilized by Se⋅⋅⋅N intramolecular interactions (such as the one in the figure) were synthesized, characterized, and examined for Se⋅⋅⋅N nonbonding interactions. A correlation between Se⋅⋅⋅N intramolecular distance and 77 Se chemical shift is attempted.